NICKEL TOXICITY & CHOLESTEROL – SCIENCE & TECHNOLOGY

NEWS: Researchers at the University of Georgia found that exposing mammalian and fungal cells to nickel leads to sterol deficiency.

 

WHAT’S IN THE NEWS?

Findings in Fungal Cells

  • Nickel Tolerance and ERG25: The fungal cells showed increased tolerance to nickel when they overexpressed the ERG25 gene, which encodes an enzyme involved in sterol biosynthesis.
  • Dependency on ERG25: Cells unable to overproduce ERG25 couldn’t grow in higher nickel concentrations, indicating the gene’s role in nickel tolerance.

Background on Nickel and Sterols

  • Nickel in Nature: Nickel is crucial for urease enzyme activity in plants, bacteria, and fungi, though it is known to be carcinogenic and an allergen in humans.
  • Role of Sterols: Sterols contribute to cell membrane rigidity. Cholesterol is the primary sterol in mammals, while ergosterol serves this role in fungi.

Use of Antifungal Drugs

  • Targeting Ergosterol: Drugs like azoles and polyenes combat fungal infections by inhibiting or binding to ergosterol, leaving cholesterol in mammals unaffected.
  • Therapeutic Relevance: This selective inhibition is what makes antifungal drugs effective without harming host cells.

Key Experiment on Cryptococcus neoformans

  • Growth in Nickel-Rich Medium: The wild-type strain of Cryptococcus neoformans could grow in a medium with high nickel concentrations, indicating an unexpected tolerance.
  • Role of Urease: Contrary to expectations, mutated strains lacking urease activity survived in nickel-rich environments, showing that urease wasn’t involved in nickel tolerance.

Discovery of Sre1’s Role

  • Mutant Screen: Researchers tested 284 C. neoformans mutants and found that only the strain lacking sterol response element 1 (Sre1) was highly sensitive to nickel.
  • Shift in Focus: This unexpected sensitivity led researchers to focus on Sre1, which regulates sterol biosynthesis genes.

Mechanism of Nickel Tolerance

  • Conservation of SRE1: The gene encoding Sre1 is conserved across animals. In mammals, it is known as SREBP (sterol regulatory element-binding protein).
  • Nickel Activation: In the study, nickel triggered cleavage of SREBP in human cells, leading to reduced cholesterol, similar to its effect on ergosterol in fungi.

ERG25 and Nickel Tolerance

  • Gene Expression Testing: Overexpression of ERG25 alone restored nickel tolerance in Sre1 mutants, suggesting its crucial role in the nickel response.
  • Similar Effects in Mammalian Cells: After 72 hours of nickel exposure, mammalian cells also exhibited reduced cholesterol, mirroring the effect seen in fungal cells.

Future Research Directions

  • Questions for Further Study: Key questions include whether ERG25 homologues in other fungi can restore nickel tolerance in mutants and whether ERG25’s sterol biosynthesis function is essential for nickel tolerance.
  • Potential for New Treatments: Understanding how ERG25 mediates nickel tolerance could lead to novel antifungal therapies by blocking the diversion of the protein from sterol synthesis to nickel tolerance.

Conclusion

  • Implications: The findings highlight a surprising connection between metal toxicity and sterol biosynthesis, with potential for new antifungal drug targets based on this pathway.

Source: https://www.thehindu.com/sci-tech/science/unexpected-link-between-nickel-toxicity-cholesterol-levels-found/article68827699.ece