CHLOROPICRIN - SCI & TECH

News: Chloropicrin: chemical weapon or pesticide?

 

What's in the news?

       The U.S. State Department has accused Russia of utilizing the chemical agent chloropicrin in Ukraine, stating that this action constitutes a breach of the Chemical Weapons Convention.

 

Chloropicrin:

       Chloropicrin, also known as nitro chloroform, serves dual roles as a warfare agent and pesticide.

 

Physical Appearance:

       It manifests as a colorless to yellow oily liquid.

 

Usage:

       Chloropicrin finds extensive application as a fungicide, herbicide, insecticide, nematicide, and antimicrobial agent.

 

Properties:

       It possesses irritant properties akin to tear gas, characterized by an intensely irritating odor.

       Its absorption can occur through inhalation, ingestion, and skin contact.

 

Historical Backdrop:

       Initially developed as a poison gas during the First World War, both the Allied and Central Powers employed chloropicrin.

 

Manufacturing Process:

       Chloropicrin is synthesized through a chemical reaction involving sodium hypochlorite (commonly known as bleach) and nitromethane, an industrial solvent.

       Alternatively, it can be produced by combining chloroform with nitric acid, resulting in chloropicrin and water.

 

Health Impacts:

       Chloropicrin is associated with documented irritative and tear-inducing effects on humans.

       Moreover, it is highly toxic, carcinogenic, and capable of inducing vomiting.

 

Go back to basics:

Chemical Weapons Convention:

       The Chemical Weapons Convention is a multilateral treaty aimed at banning chemical weapons and mandating their destruction within a specified timeframe.

       It officially entered into force on April 29, 1997.

 

Members:

       The convention is open to all nations, with 193 states currently being parties to it.

 

Provisions:

       Signatory states are required to declare their chemical weapons stockpiles, chemical weapons production facilities (CWPFs), relevant chemical industry facilities, and other weapons-related information to the Organization for the Prohibition of Chemical Weapons (OPCW).

 

India and Chemical Weapons Convention:

       India is among the signatories and parties to the Chemical Weapons Convention, having signed the treaty in Paris on January 14, 1993.

       Pursuant to the provisions of the convention, India enacted the Chemical Weapons Convention Act, 2000.